Essential Iron Man, Vol. 3 (Marvel Essentials) (v. 3)

Shellhead's rogues gallery grows during his first faceoffs with the Controller, Mordecai Midas, Firebrand and Spymaster -- all enemies destined to plague him for years to come! Meanwhile, Tony splits his life among LMD impostors, but will he lose his heart to Madame Masque? Guest-starring Daredevil, the Avengers and SHIELD!

Collecting:

Iron Man #12-38, Daredevil #73