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Electrochemical deposition of sol-gel films for enhanced chromium(VI) [An article from: Analytica Chimica Acta]
Book Details
Author(s)N.A. Carrington, L. Yong, Z.L. Xue
PublisherElsevier
ISBN / ASINB000P6O42Y
ISBN-13978B000P6O426
AvailabilityAvailable for download now
Sales Rank99,999,999
MarketplaceUnited States 🇺🇸
Description
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2006. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description:
A pyridine-functionalized sol-gel film has been formed by electrodeposition at a glassy carbon electrode surface. When this protonated film is exposed to a Cr(VI) solution, the Cr(VI) anions are preconcentrated at the electrode surface. Using square wave voltammetry, the Cr(VI) species are reduced to Cr(III), and a peak current corresponding to this reduction is generated at 0.17V. The peak currents can be correlated with the Cr(VI) concentration. The functionalized sol-gel films demonstrated an enhanced sensitivity for Cr(VI) in aqueous solutions, providing a limit of detection at the low ppb level. Interference studies also displayed the high selectivity of the films for Cr(VI), and the system was able to tolerate a large excess of Cr(III) with no adverse affects. The reported electrodeposition method of film formation uses commercially available reagents and yields films quickly and reproducibly. The growth of these sol-gel films was monitored using an electrochemical quartz crystal microbalance (EQCM), and they were characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The reported work shows the promise of such an electrode for use in Cr(VI) sensing applications.
Description:
A pyridine-functionalized sol-gel film has been formed by electrodeposition at a glassy carbon electrode surface. When this protonated film is exposed to a Cr(VI) solution, the Cr(VI) anions are preconcentrated at the electrode surface. Using square wave voltammetry, the Cr(VI) species are reduced to Cr(III), and a peak current corresponding to this reduction is generated at 0.17V. The peak currents can be correlated with the Cr(VI) concentration. The functionalized sol-gel films demonstrated an enhanced sensitivity for Cr(VI) in aqueous solutions, providing a limit of detection at the low ppb level. Interference studies also displayed the high selectivity of the films for Cr(VI), and the system was able to tolerate a large excess of Cr(III) with no adverse affects. The reported electrodeposition method of film formation uses commercially available reagents and yields films quickly and reproducibly. The growth of these sol-gel films was monitored using an electrochemical quartz crystal microbalance (EQCM), and they were characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The reported work shows the promise of such an electrode for use in Cr(VI) sensing applications.
