![Slurry sampling electrothermal vaporization inductively coupled plasma mass spectrometry for the determination of As and Se in soil and sludge [An article from: Analytica Chimica Acta]](https://www.ebooknetworking.net/books/B00/0PD/bigB000PDYMN8.jpg)
Slurry sampling electrothermal vaporization inductively coupled plasma mass spectrometry for the determination of As and Se in soil and sludge [An article from: Analytica Chimica Acta]
Book Details
Author(s)Y.J. Tseng, C.C. Liu, S.J. Jiang
PublisherElsevier
ISBN / ASINB000PDYMN8
ISBN-13978B000PDYMN2
MarketplaceGermany 🇩🇪
Description
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2007. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description:
Slurry sampling electrothermal vaporization (ETV) inductively coupled plasma mass spectrometry (ICP-MS) has been applied to determine As and Se in soil and sludge samples. The influences of instrument operating conditions and slurry preparation on the ion signals were reported. Pd and ascorbic acid were used as mixed modifiers to enhance the ion signals. The effectiveness of ETV sample introduction technique for alleviating various spectral interferences in ICP-MS analysis has been demonstrated. This method has been applied to determine As and Se in NIST SRM 2709 San Joaquin soil reference material and NIST SRM 2781 domestic sludge reference material and a farmland soil sample collected locally. Since the sensitivities of As and Se in slurry solution and aqueous solution were different, analyte addition technique was used to determine As and Se in these samples. The As and Se analysis results of the reference materials agreed with the certified values. The precision between sample replicates was better than 5% for all determinations. The method detection limit estimated from analyte addition curves was about 0.03 and 0.02@mgg^-^1 for As and Se, respectively, in original soil and sludge samples.
Description:
Slurry sampling electrothermal vaporization (ETV) inductively coupled plasma mass spectrometry (ICP-MS) has been applied to determine As and Se in soil and sludge samples. The influences of instrument operating conditions and slurry preparation on the ion signals were reported. Pd and ascorbic acid were used as mixed modifiers to enhance the ion signals. The effectiveness of ETV sample introduction technique for alleviating various spectral interferences in ICP-MS analysis has been demonstrated. This method has been applied to determine As and Se in NIST SRM 2709 San Joaquin soil reference material and NIST SRM 2781 domestic sludge reference material and a farmland soil sample collected locally. Since the sensitivities of As and Se in slurry solution and aqueous solution were different, analyte addition technique was used to determine As and Se in these samples. The As and Se analysis results of the reference materials agreed with the certified values. The precision between sample replicates was better than 5% for all determinations. The method detection limit estimated from analyte addition curves was about 0.03 and 0.02@mgg^-^1 for As and Se, respectively, in original soil and sludge samples.
