![Enhanced electrochemiluminescence from Os(phen)"2(dppene)^2^+ (phen=1,10-phenanthroline and dppene=bis(diphenylphosphino)ethene) in the presence of ... [An article from: Analytica Chimica Acta]](https://www.ebooknetworking.net/books/B00/0RR/bigB000RR02W2.jpg)
Enhanced electrochemiluminescence from Os(phen)"2(dppene)^2^+ (phen=1,10-phenanthroline and dppene=bis(diphenylphosphino)ethene) in the presence of ... [An article from: Analytica Chimica Acta]
Book Details
Author(s)
J. Walworth, K.J. Brewer, M.M. Richter
Publisher
Elsevier
ISBN / ASIN
B000RR02W2
ISBN-13
978B000RR02W0
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Available for download now
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United States 🇺🇸
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Description
This digital document is a journal article from Analytica Chimica Acta, published by Elsevier in 2004. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description:
The effects of the non-ionic surfactant Triton X-100 (polyethylene glycol tert-octylphenyl ether) on the properties of Os(phen)"2(dppene)^2^+ (phen=1,10-phenanthroline and dppene=bis(diphenylphosphino)ethene) electrochemiluminescence (ECL) have been investigated. The anodic oxidation of Os(phen)"2(dppene)^2^+ produces ECL in the presence of tri-n-propylamine (TPrA) in aqueous surfactant solution. Increases in ECL efficiency (>=3-fold) and TPrA oxidation current (>=2.0-fold) have been observed in surfactant media with experiments supporting adsorption of surfactant on the electrode surface.
Description:
The effects of the non-ionic surfactant Triton X-100 (polyethylene glycol tert-octylphenyl ether) on the properties of Os(phen)"2(dppene)^2^+ (phen=1,10-phenanthroline and dppene=bis(diphenylphosphino)ethene) electrochemiluminescence (ECL) have been investigated. The anodic oxidation of Os(phen)"2(dppene)^2^+ produces ECL in the presence of tri-n-propylamine (TPrA) in aqueous surfactant solution. Increases in ECL efficiency (>=3-fold) and TPrA oxidation current (>=2.0-fold) have been observed in surfactant media with experiments supporting adsorption of surfactant on the electrode surface.
