Removal of cadmium from wastewater using agricultural waste 'rice polish' [An article from: Journal of Hazardous Materials]
Book Details
Author(s)K.K. Singh, R. Rastogi, S.H. Hasan
PublisherElsevier
ISBN / ASINB000RR45I4
ISBN-13978B000RR45I5
AvailabilityAvailable for download now
MarketplaceUnited States 🇺🇸
Description
This digital document is a journal article from Journal of Hazardous Materials, published by Elsevier in 2005. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.
Description:
A novel biosorbent rice polish has been successfully utilized for the removal of cadmium(II) from wastewater. The maximum removal of cadmium(II) was found to be 9.72mgg^-^1 at pH 8.6, initial Cd(II) concentration of 125mgl^-^1 and temperature of 20^oC. The effect of different parameters such as contact time, adsorbate concentration, pH of the medium and temperature were investigated. Dynamics of the sorption process were studied and the values of rate constant of adsorption, rate constant of intraparticle diffusion and mass transfer coefficient were calculated. Different thermodynamic parameters, viz., changes in standard free energy, enthalpy and entropy have also been evaluated and it has been found that the reaction was spontaneous and exothermic in nature. The applicability of Langmuir isotherm showed monolayer coverage of the adsorbate on the surface of adsorbents. A generalised empirical model was proposed for the kinetics at different initial concentrations. The data were subjected to multiple regression analysis and a model was developed to predict the removal of Cd(II) from wastewater.
Description:
A novel biosorbent rice polish has been successfully utilized for the removal of cadmium(II) from wastewater. The maximum removal of cadmium(II) was found to be 9.72mgg^-^1 at pH 8.6, initial Cd(II) concentration of 125mgl^-^1 and temperature of 20^oC. The effect of different parameters such as contact time, adsorbate concentration, pH of the medium and temperature were investigated. Dynamics of the sorption process were studied and the values of rate constant of adsorption, rate constant of intraparticle diffusion and mass transfer coefficient were calculated. Different thermodynamic parameters, viz., changes in standard free energy, enthalpy and entropy have also been evaluated and it has been found that the reaction was spontaneous and exothermic in nature. The applicability of Langmuir isotherm showed monolayer coverage of the adsorbate on the surface of adsorbents. A generalised empirical model was proposed for the kinetics at different initial concentrations. The data were subjected to multiple regression analysis and a model was developed to predict the removal of Cd(II) from wastewater.
