Synthesis and properties of novel copolymers of poly(ether ketone ether ketone ketone) and poly(ether amide amide ether ketone ketone).(Report): An article from: Polymer Engineering and Science
Book Details
PublisherSociety of Plastics Engineers, Inc.
ISBN / ASINB00GSHEGL8
ISBN-13978B00GSHEGL2
AvailabilityAvailable for download now
Sales Rank99,999,999
MarketplaceUnited States 🇺🇸
Description
This digital document is an article from Polymer Engineering and Science, published by Society of Plastics Engineers, Inc. on November 1, 2013. The length of the article is 5223 words. The page length shown above is based on a typical 300-word page. The article is delivered in HTML format and is available immediately after purchase. You can view it with any web browser.
From the author: A new monomer, N, N'-bis(4-phenoxybenzoyI)-m-phenylenediamine (BPMPDA), was prepared via the reaction of m-phenylenediamine with 4-phenoxybenzoyl chloride in N,N-dimethylacetamide. Novel copolymers of poly(ether ketone ether ketone ketone) and poly (ether amide amide ether ketone ketone) (PEAAEKK) were synthesized by the modified electrophilic Friedel-Crafts acylation copolycondensation of terephtha-loyl chloride with a mixture of 4,4'-diphenoxybenzo-phenone (DPOBPN) and BPMPDA, over a wide range of DPOBPN/BPMPDA molar ratios. The resulting copolymers were characterized by Fourier transform infrared spectroscopy, wide-angle X-ray diffraction, differential scanning calorimetry, and thermogravimetric analysis, and so on. The results indicated that the copolymers with 10-30 mol% BPMPDA were semi-crystalline and had remarkably increased glass transition temperatures ([T.sub.g]s) over the conventional poly (ether ether ketone) and poly(ether ketone ketone) due to the incorporation of amide linkages in the main chains. The copolymers III and IV with 20-30 mol% BPMPDA had not only high [T.sub.g]s of 177-180 [degrees]C, but also moderate melting temperatures ([T.sub.m]s) of 324-333 C, having good potential for the melt processing. The copolymers III and IV had tensile strengths of 101.8104.4 MPa, Young's moduli of 2.32-2.46 GPa, and elongations at break of 10.8-12.2% and exhibited high thermal stability and excellent resistance to organic solvents. POLYM. ENG. SCI., 53:2353-2359, 2013. [c] 2013 Society of Plastics Engineers
Citation Details
Title: Synthesis and properties of novel copolymers of poly(ether ketone ether ketone ketone) and poly(ether amide amide ether ketone ketone).(Report)
Author: Jiangping Qian
Publication:Polymer Engineering and Science (Magazine/Journal)
Date: November 1, 2013
Publisher: Society of Plastics Engineers, Inc.
Volume: 53 Issue: 11 Page: 2353(7)
Article Type: Report
Distributed by Gale, a part of Cengage Learning
From the author: A new monomer, N, N'-bis(4-phenoxybenzoyI)-m-phenylenediamine (BPMPDA), was prepared via the reaction of m-phenylenediamine with 4-phenoxybenzoyl chloride in N,N-dimethylacetamide. Novel copolymers of poly(ether ketone ether ketone ketone) and poly (ether amide amide ether ketone ketone) (PEAAEKK) were synthesized by the modified electrophilic Friedel-Crafts acylation copolycondensation of terephtha-loyl chloride with a mixture of 4,4'-diphenoxybenzo-phenone (DPOBPN) and BPMPDA, over a wide range of DPOBPN/BPMPDA molar ratios. The resulting copolymers were characterized by Fourier transform infrared spectroscopy, wide-angle X-ray diffraction, differential scanning calorimetry, and thermogravimetric analysis, and so on. The results indicated that the copolymers with 10-30 mol% BPMPDA were semi-crystalline and had remarkably increased glass transition temperatures ([T.sub.g]s) over the conventional poly (ether ether ketone) and poly(ether ketone ketone) due to the incorporation of amide linkages in the main chains. The copolymers III and IV with 20-30 mol% BPMPDA had not only high [T.sub.g]s of 177-180 [degrees]C, but also moderate melting temperatures ([T.sub.m]s) of 324-333 C, having good potential for the melt processing. The copolymers III and IV had tensile strengths of 101.8104.4 MPa, Young's moduli of 2.32-2.46 GPa, and elongations at break of 10.8-12.2% and exhibited high thermal stability and excellent resistance to organic solvents. POLYM. ENG. SCI., 53:2353-2359, 2013. [c] 2013 Society of Plastics Engineers
Citation Details
Title: Synthesis and properties of novel copolymers of poly(ether ketone ether ketone ketone) and poly(ether amide amide ether ketone ketone).(Report)
Author: Jiangping Qian
Publication:Polymer Engineering and Science (Magazine/Journal)
Date: November 1, 2013
Publisher: Society of Plastics Engineers, Inc.
Volume: 53 Issue: 11 Page: 2353(7)
Article Type: Report
Distributed by Gale, a part of Cengage Learning
